Shivangi Parashar 2 just take a tree and try to go from one node to any other node , you will find it UNIQUE. Actually it is a theorem. If you want proof visit this http://www.cs.cmu.edu/afs/cs/academic/class/15251/Site/current/Materials/Handouts/lecture20-proofs.pdf
We can prove this by contradiction. Let us assume that there exists more than one path from a vertex $i$ to vertex $j$. If we take the union of these two paths, we will form a cycle, which contradicts the fact that we have a tree. Hence, there can be only one unique path for every pair of vertices. For more such proofs, see here: http://compalg.inf.elte.hu/~tony/Oktatas/TDK/FINAL/Chap%204.PDF
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