@Verma Ashish Take $3$ vertices...and if you don't give them a name like $A$,$B$ and $C$ and when you try to make simple graphs with these vertices then some graphs will be isomorphic and when you give them a name then all possible graphs will be considered as distinct graphs...
There is no closed form formula to find no. of unlabeled simple graphs with $n$ vertices but we can find no. of simple graphs with $n$ labeled vertices as you have given above. Since, maximum edges are $^{n}C_{_{2}}$. So, 2 choices for choosing each edge. So, it becomes $2^{^{n}C_{_{2}}}$
There is no closed form formula to find no. of unlabeled simple graph with $n$ vertices but it will always be less than $2^{^{n}C_{_{2}}}$ because some graphs will be same due to its isomorphic nature.