nephron just took a small example let A ={1,2,3}
now read question R shoulb be irreflexive so no (a,a) type pairs should be there .
now to be symmetric if (a,b) is there (b,a) should be there
;let write all such pairs R={(1,2),(2,1),(1,3),(3,1) and so on...........}
now this R should be transitivw also so is (1,2) and (2,1) is present then (1,1) shoulb be also present which is impossible due to irreflexive nature hence phi is only element.