Functionally complete: A collection of logical operators is called functionally complete if every compound proposition is logically equivalent to a compound proposition involving only these logical operator.
Suppose, we prove that (p$\wedge$q) $\equiv\,\sim$($\sim$p $\vee\sim$q) .
proof: (p$\wedge$q)
=$\sim$($\sim$(p$\wedge$q)) by applying Double Negation Law,
=$\sim$($\sim$p $\vee\sim$q) by applying demorgan law,
Hence, proved.
Now, we can say that $\sim$ ,$\vee$ are functionally complete because resultant compound proposition $\sim$($\sim$p $\vee\sim$q) contain only these logical operator.