There are total 7C2 = 21 pairs eligible for symmetric relations.
These pairs are of form {(a,b) (b,a)}. This pair consists of 2 ordered pair (a,b) and (b,a).
Also ordered pair of form (a,a) is also eligible for symmetric relations. There are total 7 such pairs.
Now,
Total number of symmetric relations which contains exactly 4 ordered pair =
7C4 + //4 ordered pairs of form (a,a)
21C2 + //2 pairs of form {(a,b) (b,a)} which will give 4 ordered pairs
21C1 * 7C2 //1 pair of form {(a,b) (b,a)} and 2 ordered pairs of form (a,a)
= 686.